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41.
The Upper Jurassic Tordillo Formation is exposed along the western edge of the Neuquén Basin (west central Argentina) and consists of fluvial strata deposited under arid/semiarid conditions. The pebble composition of conglomerates, mineralogical composition of sandstones and pelitic rocks, and major- and trace-element geochemistry of sandstones, mudstones, and primary pyroclastic deposits are evaluated to determine the provenance and tectonic setting of the sedimentary basin. Conglomerates and sandstones derived almost exclusively from volcanic sources. The stratigraphic sections to the south show a clast population of conglomerates dominated by silicic volcanic fragments and a predominance of feldspathic litharenites. This framework composition records erosion of Triassic–Jurassic synrift volcaniclastic rocks and basement rocks from the Huincul arch, which was exhumed as a result of Late Jurassic inversion. In the northwestern part of the study area, conglomerates show a large proportion of mafic and acidic volcanic rock fragments, and sandstones are characterised by a high content of mafic volcanic rock fragments and plagioclase. These data suggest that the source of the sandstones and conglomerates was primarily the Andean magmatic arc, located west of the Neuquén Basin. The clay mineral assemblage is interpreted as the result of a complex set of factors, including source rock, climate, transport, and diagenesis. Postdepositional processes produced significant variations in the original compositions, especially the fine-grained deposits. The Tordillo sediments are characterised by moderate SiO2 contents, variable abundances of K2O and Na2O, and a relatively high proportion of ferromagnesian elements. The degree of chemical weathering in the source area, expressed as the chemical index of alteration, is low to moderate. The major element geochemistry and Th/Sc, K/Rb, Co/Th, La/Sc, and Cr/Th values point to a significant input of detrital volcanic material of calcalkaline felsic and intermediate composition. However, major element geochemistry is not useful for interpreting the tectonic setting. Discrimination plots based on immobile trace elements, such as Ti, Zr, La, Sc, and Th, show that most data lie in the active continental margin field. Geochemical information is not sufficiently sensitive to differentiate the two different source areas recognized by petrographic and modal analyses of conglomerates and sandstones.  相似文献   
42.
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions.  相似文献   
43.
Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km2 of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph) in the Sarria River basin (155 km2, NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number) by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling (one-phase, one-dimensional and steady flow) in a 4 km2 urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both methods. Originally presented at the Sixth International Conference on Geomorphology.  相似文献   
44.
Gravitational spreading of mountain ridges displays primary disequilibrium of flysch mountain areas of the Czech Carpathians. The progression of various types of mass movements is a product of long-term ridge disintegration and is predisposed by the geological structure of the area and the upper Tertiary-Quaternary morphogenesis of the mountain area. Deep-seated slope deformations are spatially interconnected by the occurrence of some other types of slope deformations (e.g. debris flows, debris slides, slumps, rock avalanches, etc.), which pose a considerable risk for the existence of human society. An important causative factor in these dynamically developing hazardous processes is, among other factors, the way in which land has been used in the last three centuries. Therefore, the occurrence of various types of slope deformations is studied in terms of their relation to deep-seated gravitational deformations and in terms of other limiting factors (structural geological, morphological and climatic factors, manmade impacts, etc.). The paper presents several case studies of slope deformations (Velká Čantoryje Mt, Lysá hora Mt, Ropice Mt and Smrk Mt) in the area of the Outer Carpathians within the territory of the Czech Republic and also adverts to some consequences in terms of the socioeconomic structure of the landscape.  相似文献   
45.
A detailed study was carried out on a piece of land that had been struck by lightning during the violent rainstorm that raged over the Island of S?o Miguel (Azores Archipelago) in late October 2006. Temperature and gas measurements (CO2, CO, H2S and CH4) were performed in four study trenches, dug in an area of ∼3 m2, where an underground fire had been initiated by the impact with a lightning stroke, followed by the emission of a column of gases and smoke. The soil under study was originally a well-pedogenized about 80 cm thick bed, made of volcanic clayey to silty tephra fallouts and contained 5.5–9.7% of organic matter. The underground fire was monitored for one week and revealed a peak release of 404 ppm CO and 3.4% CO2 originating from a horizon located about 45 cm under the soil surface. Measurements of temperature, performed one week after the impact, indicated a maximum value of 326°C inside the soil, while 516.5°C were measured on the surface of a lava block interred about 20 cm under the surface. Subsequently, a stratigraphic and sedimentologic study proved the role of the grain-size of the soil and of the organic matter content of the different horizons of the impact area, in determining the ratio between anoxic/oxidised combustion conditions and in the progress of the process itself. It was also noticed that combustion was not total all over in the soil bed and that the process had slightly migrated toward SW during the observation period. The combustion process went on for about ten days, in spite of several other violent rainstorms, until it was artificially extinguished through the excavations made to obtain study trenches. This particular circumstance evidenced the potential natural hazard represented by this kind of atmospheric event, especially in a land where the volcanic nature of the soil may easily mislead inexperienced observers and, consequently, delay proper action.  相似文献   
46.
47.
A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (18O, 2H and 3H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.  相似文献   
48.
49.
Summary The process of radon diffusion in space and time through rocks is treated in detail from the point of view of radiometric prospecting for oil. Taking into account the depth and diffusivity conditions encountered in nature it is stated that vertical radon diffusion reaching from the oil deposits up to the surface cannot be expected. Time intervals as required for setting in of a stationary concentration state and decay conditions of the radon lead to the conclusion that the penetration of emanometric measurements seldom exceeds the depth of 5–10 m.  相似文献   
50.
Zusammenfassung Es werden mit Hilfe der sphärischen Trigonometrie und der Ausgleichsrechnung Methoden angegeben, die die Berechnung der bestanschmiegenden Ebene an eine Anzahl von Geraden mit einem gemeinsamen Punkt ermöglichen.
Summary With the aid of the spherical trigonometry and the adjustment, methods are given to determin the best-fitting plane for a given set of directions through a common point.
  相似文献   
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